Cotton is a natural fiber, which absorbs and retains moisture, often causing the skin to become macerated and wrinkled–just like what happens to the skin when it is submerged in a pool or bathtub for a long time.  Wet skin is more likely to form blisters, which is why cotton socks should be avoided.
Wear acrylic or synthetic socks that don’t retain moisture. These socks wick away moisture from your foot and help keep them dry and healthy.
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Photo by andy_5322 on Flickr